SHERWIN-WILLIAMS -- 1001122 ACE WHT STRIPING PAINT, W2553520 -- 8010-00N091782
===================== Product Identification ===================== Product ID:1001122 ACE WHT STRIPING PAINT, W2553520 MSDS Date:03/03/1994 FSC:8010 NIIN:00N091782 Status Code:A === Responsible Party === Company Name:SHERWIN-WILLIAMS Address:31500 SOLON ROAD City:SOLON State:OH ZIP:44139 Country:US Info Phone Num:800-247-3270 Emergency Phone Num:216-292-7400 CAGE:09800 === Contractor Identification === Company Name:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC. Address:26300 FARGO AVENUE Box:City:BEDFORD HEIGHTS State:OH ZIP:44146 Country:US Phone:216-292-7400 OR 216-595-8634 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE. VP: 760. CAS:74-98-6 RTECS #:TX2275000 = Wt:9. OSHA PEL:1800 MG/M3;1000 PPM Ingred Name:2-METHYLPROPANE. VP: 760. CAS:75-28-5 RTECS #:TI4300000 = Wt:11. Ingred Name:HYDROTREATED HEAVY NAPHTHA (PETROLEUM); (VM&P NAPHTHA) VP:12. CAS:8032-32-4 = Wt:3. OSHA PEL:300 PPM OSHA STEL:400 PPM ACGIH TLV:1370 MG/M3;300 PPM Ingred Name:XYLENE. VP:5.9. CAS:1330-20-7 RTECS #:ZE2100000 = Wt:15. OSHA PEL:100 PPM OSHA STEL:150 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHANOL. VP:92.. CAS:67-56-1 RTECS #:PC1400000 = Wt:2. OSHA PEL:260 MG/M3;200 PPM OSHA STEL:250 PPM, S ACGIH TLV:262 MG/M3;200 PPM ACGIH STEL:328 MG/M3;250 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETONE. VP: 180. CAS:67-64-1 RTECS #:AL3150000 = Wt:16. Other REC Limits:OSHA PEL:750 PPM(M). OSHA PEL:2400 MG/M3;1000 PPM OSHA STEL:1000 PPM ACGIH TLV:1780 MG/M3;750 PPM ACGIH STEL:2380 MG/M3;1000 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CALCIUM CARBONATE CAS:471-34-1 RTECS #:FF9335000 = Wt:5. Other REC Limits:PEL:5 MG/M3 RDUST(M) OSHA PEL:15 MG/M3 (TDUST) ACGIH TLV:10 MG/M3 Ingred Name:BARIUM SULFATE. OSHA PEL: 10 MG/M3 (TDUST); 5 MG/M3 (RDUST) (M). CAS:7727-43-7 RTECS #:CR0600000 = Wt:3. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:TITANIUM DIOXIDE. OSHA PEL: 10 MG/M3 (TDUST); 5 MG/M3 (RDUST) (M). CAS:13463-67-7 RTECS #:XR2275000 = Wt:17. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:BARIUM CAS:7440-39-3 RTECS #:CQ8370000 = Wt:1. ACGIH TLV:0.5 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EXPOSURE MAY BE BY INHALATION AND/OR SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF USE. TO MINIMIZE EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTILATION AND PERSONAL PROTECTIVE EQUIPMENT. AC UTE: IRRITATION OF EYES, SKIN AND RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH. HEADACHE, DIZZINESS, NAUSEA AND LOSS O F COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS. REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. CHRONIC: PROLONGED OVEREXPOSURE (EF TS OF OVEREXP) Explanation of Carcinogenicity:NO INGREDIENT IN THIS PRODUCT IS AN IARC, NTP OR OSHA LISTED CARCINOGEN. Effects of Overexposure:HLTH HAZ: TO SOLVENT INGREDIENTS MAY CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY AND REPRODUCTIVE SYSTEMS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS URE LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENT WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATEL Y CONCENTRATING AND INHALING CONTENTS CAN BE HARMFUL OR FATAL. Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH W ITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:<-17.8C, 0.F PROPELLANT Lower Limits:0.9% Upper Limits:36.5% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESS URE BUILD-UP & POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS REQS SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. HMIS CODES: HLTH - 3; FLAMMABILITY - 4; REACTIVITY - 0. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. ====================== Handling and Storage ====================== Handling and Storage Precautions:DOL STORAGE CATEGORY: 1A. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCS. CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN/EXPOSE TO TEMP >120F. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. Other Precautions:KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA VENTED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATER S; TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. HEAT FROM SUNLIGHT, RADIAT ORS, STOVES,(SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED NIOSH APPROVED ORGANIC VAPOR/PARTICULATE RESPIRATOR FOR PROTECTION AGAINST INGREDIENTS. WHEN SA NDING OR ABRADING DRIED FILM, WEAR A NIOSH APPROVED DUST/MIST RESPIRATOR FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT, UNDERLYING PAINT, OR THE ABRASIVE. Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF EXPOS TO INGS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STD 1910.94, 1910.107, 1910.108. Protective Gloves:CHEMICAL RESISTANT GLOVES. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health OTHER PREC:HOT WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. ADDN OF REDUCERS/OTHER ADDITIVES TO THIS PROD MAY SUBSTANTIALLY ALTER COMPOSITION & HAZS OF PROD. THIS COATING MAY CONTAIN MATLS C LASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF (OTHER INFO) ================== Physical/Chemical Properties ================== Boiling Pt:<162.8C, 325.F B.P. Text:<0-325F Vapor Pres:SEE INGREDIENTS Vapor Density:HVR/AIR Spec Gravity:0.95 Evaporation Rate & Reference:FASTER THAN ETHER Percent Volatiles by Volume:77 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:SKIN IRRITATION: NO INFORMATION IS AVAILABLE. EYE IRRITATION: NO INFORMATION IS AVAILABLE. ACUTE TOXICITY (LD50): LD50: (ORAL, RAT) 6.8 G/KG (ACETONE: DECOMPOSED PRODUCT). ACUTE TOXICITY (LC50): LC50: (INHALATION/RAT) 50.1 G/M3/8HR (ACETONE: DECOMPOSED PRODUCT). CHRONIC TOXICITY: NO INFORMATION IS AVAILABLE. CARCINOGENICITY: NTP: NOT LISTED. IARC: NOT LISTED. OSHA REGULATED: NOT LISTED. OTHER INFO RMATION: NONE. ===================== Ecological Information ===================== Ecological:BIODEGRADATION: NOT APPLICABLE. BIOACCUMULATION: NO INFORMATION IS AVAILABLE. AQUATIC TOXICITY: NO INFORMATION IS AVAILABLE. OTHER INFORMATION: NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLICABLE EPA HAZARDOUS WAST E NUMBERS. DO NOT INCINERATE. DEPRESSURIZE CONTAINER. DISPOSE OF I/A/W FEDERAL, STATE & LOCAL REGULA TIONS REGARDING POLLUTION. =================== MSDS Transport Information =================== Transport Information:UN NO: NONE. (THIS PRODUCT MAY TAKE FIRE BY LITTLE EVOLVED FLAMMABLE VAPOR WHEN THE CONTAINER IS OPENED AND THE IGNITION SOURCES ARE BROUGHT CLOSE TO THIS PRODUCT. BUT IT DOES NOT CONTINUE BURNING AND CONTRIBUTE TO FIRE.) IMO CLASSIFICATION AND CLASS: NONE. PACKAGING GROUP: NONE. PROPER SHIPPING NAME: NONE. TECHNICAL SHIPPING NAME: NONE. MARINE POLLUTANT: NONE. HAZARD SUBSTANCE(S) NAME/CAS NO, CON TENTS AND RQ: NOT APPLICABLE. ===================== Regulatory Information ===================== SARA Title III Information:SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION: CAS NO: 1330-20-7, CHEMICAL/COMPOUND: XYLENE, % BY WT: 15; CAS NO: 67-56-1, CHEMICAL/COMPOUND: METHANOL, % BY WT: 2; CAS NO: 67-64-1, CHEMICAL/COMPOUND : ACETONE, % BY WT: 15; CHEMICAL/COMPOUND: BARIUM, % ELEMENT: 1. State Regulatory Information: ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.